Synthesis and chiroptical properties of organometallic complexes of helicenic N ‐heterocyclic carbenes
نویسندگان
چکیده
منابع مشابه
Synthesis of Ru(II) complexes of N-heterocyclic carbenes and their promising photoluminescence properties in water.
Novel complexes 1 and 2 based on N-heterocyclic carbenes, which are analogous to Ru(bpy)(3)(2+) and Ru(terpy)(2)(2+), respectively, were synthesized. The complex, which is analogous to Ru(terpy)(2)(2+), exhibited promising photoluminescence properties with a long lifetime of 820 ns in acetonitrile and 3100 ns in water at room temperature, respectively. In addition, ab initio calculations were c...
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The N-heterocyclic carbenes (NHC) now hold a preferredligand status in organic and organometallic chemistry. Their role in catalysis continues to grow. When the editorial staff at the Beilstein Journal of Organic Chemistry contacted me to act as a guest editor for the thematic series “N-Heterocyclic carbenes”, I was more than happy to accept what appeared to me to be a simple and exciting endea...
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ژورنال
عنوان ژورنال: Chirality
سال: 2019
ISSN: 0899-0042,1520-636X
DOI: 10.1002/chir.23143